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Saturday Review.-"The book is one of the most original and enter taining in recent anthropological literature." London: PATERNOSTER HOUSE, CHARING CROSS ROAD. THURSDAY, DECEMBER 1, 1892. CHEMICAL LECTURE EXPERIMENTS. comes forward to give the lecturer of to-day a helping hand. The first thing that strikes one on looking through his pages, is how simple are the experiments-so far as illustrating the chemistry of the non-metals goes, and he goes no further-needed to illustrate a course of lectures. Chemical Lecture Experiments. By G. S. Newth. We do not require the expensive and delicate instru(Longmans, 1892.) ments of the physicist. With glass and india-rubber, as "ON revient toujours," &c. and the very description Liebig said, we chemists perform all our mysteries. Only of a good lecture experiment to one who had for thirty years always enjoyed performing an old one, and was overjoyed in bringing out a new one, is some. thing akin to that of the old war-horse when he scents the battle from afar. And both Mr. Newth's experiments and his descriptions are good; so I think that not only the novices of the profession but the old hands will read this book-the first with profit with a view to what they will do, and the second with pleasure in recollecting what they have done. I was dining some years ago with the great Dumas (I don't mean either of the novelists), and after dinner we sat together on the sofa smoking our cigars, when he said to me, "I have been in many positions-professor, minister of state, and investigator-and I have seen the world from many points of view. If I had to live my life again I would not leave my laboratory. The greatest pleasure in my life has been original work; the second greatest that of teaching a class who appreciated what I was telling them." We all know that Dumas was a master in the art of experimental teaching, and those who have practised this art, even at a great distance from the master, will agree with him that the pleasure of giving a well-illustrated experimental lecture on chemistry is not a small one, and even that a man may go on for thirty years and yet not be altogether tired of the job. The reason for this is not far to seek. Our science in its daily progress constantly opens up new paths which yield matter suitable for lecture experiment, and this gives a zest to the discourse unattainable by the teachers of most other subjects. Mr. Newth has collected an ample store, and he has described them clearly. For the collection he has had favourable opportunity; to begin with he was a distinguished student at Owens, and there he may have picked up a few wrinkles; then he has for many years been Lecture Demonstrator to Frankland and Thorpe, and from them the wrinkles he has picked up have certainly been many. But although doubtless some are of his own finding out, I think it would have been well if he had added after the description of each experiment the name of the authority with whom it originated. Thus some have been described by the chemists I have named, others owe their existence to Hofmann, Bunsen, and others. These additions are not only due to the authors, but would add to the interest of the book. Mr. Newth should see to this in the next edition. The old booksellers tell us that Faraday's "Manipulations" is a work which no lecturer should be without, and as everything which that prince of experimenters wrote or did is worthy of attention, they speak truly, and yet no modern chemists can be bound by Faraday's experience of sixty years ago. Things are not as they were; and the methods of work and the illustrations of chemical phenomena which he details belong to a bygone age. And so Mr. Newth in a few cases, as, for instance, when we want to hand round wine-glasses filled with liquefied oxygen or air, or when we desire to show our students free fluorine and such like things, does the apparatus become expensive or the experiments troublesome. All the ordinary and many of the extraordinary experiments detailed in the book may be carried out with little cost and without great trouble; indeed most of them may be made by the veriest tyro provided he stick to the letter of the description and does not attempt to vary the proceedings, as one I knew did, who thought that as sulphuric acid is a more powerful desiccating agent than lime, he would dry his ammonia by the former substance instead of by the latter material. No account of any experiment, the author tells us, has been introduced upon the authority solely of any verbal or printed description, but every experiment has been the subject of his personal investigation and the illustrations are taken from his original drawings, so that we may be sure that every experiment will "go" if properly managed and fairly dealt with. Many of the experiments are, of course, old stagers, but none the less useful, whilst others are new to me and probably to most people. To mention many either old or new this is not the place, but one of them, which has struck me as interesting is an easy method of showing the freezing of water by its own evaporation first with a common air-pump, and second with no air-pump at all. I always used a Carre's machine, by which a quart of water could be frozen, but Mr. Newth gives an excellent description of how a beautiful icicle twenty to thirty centimetres long can be obtained both with and without an air-pump. The secret of how to do this can best be learnt by reading pages 57 to 59 of the book. "How to float soap bubbles upon carbon dioxide has often proved a difficult question to answer experimentally, because if you managed, after a score of trials, to free your bubble from the pipe on which you blew it, the bubble usually bursts the moment it touches your heavy gas. Mr. Newth lets us into the secret. You must remove every trace of hydrochloric acid,which is carried over with the gas, by washing, the presence of this acid being fatal to the life of a soap bubble. Under chlorine (p. 88) a description is given of the mode of sealing up bulbs filled with chlorine and hydrogen. This was first done in the early sixties by my old helper and friend Mr. Joseph Heywood, of Owens, to whom both students and lecturers owe many an ingenious and striking experimental illustration. As Mr. Newth remarks, there are many obvious reasons why the old plan of filling a soda-water bottle with a mixture of equal volumes of the gases and then throwing it out of the lecture-room window into the street, if the sun happened to shine, is "unsuitable for a lecture experiment," and Heywood's bulbs answer the purpose better in all respects. The author does not tell us-as he ought to have done that Victor Meyer now seals up bulbs of oxygen and hydrogen (electrolytic gas) in a similar way, and that these, like their confrères of Cl and H, can be kept not only in the dark for any time, but, unlike these, also in the light without undergoing any change. The fact that many gases when perfectly dry do not combine is illustrated by the case of chlorine and metals-brass and sodium, pp. 84 and 85-as well as of carbon monoxide and oxygen, for these gases will not explode if dry, p. 189. A more striking way of illustrating this latter case than that with the eudiometer is not mentioned. I will add it. Dry a current of carbonic oxide over glass balls moistened with strong sulphuric acid; light the stream of gas issuing from a horizontal tube; then plunge over the blue flame a cylinder full of air which has been previously dried by shaking it up with a little strong sulphuric acid. The flame instantly goes out. Another case of the kind observed by Arnold lends itself to a lecture experiment. He found that powdered iron will not burn in pure dry oxygen, and in order to be able to estimate hydrogen in iron it was found necessary to insert a small tube containing a drop of water, through which the oxygen passed before coming into contact with the iron, this tube being of course weighed both before and after the experiment. This may well be included in the next edition, which I hope will soon be called for. Another capital experiment to show that iron can be carbonized by contact with a diamond was recently described to me by Mr. Gilbert Fowler, of Owens. A loop of pure thin iron wire is placed in a vertical glass tube surrounded by an atmosphere of hydrogen. Below the loop is a splinter diamond (or some diamond dust) placed on the top of a glass rod working through the lower end of the tube. After heating the wire by a current to the highest possible temperature without fusion, bring the diamond carefully into contact with the heated iron. The metal at once fuses. But of good experiments "there is no end" (Mr. Newth describes 620 for the non-metals alone) whilst of a review of a book in NATURE there must be a speedy end, and I will end by advising all those who like to see and to show good experiments to get Mr. Newth's book. H. E. ROSCOE. A MANUAL OF PHOTOGRAPHY. A Manual of Photography. By A. Brothers, F.R.A.S. (London: Charles Griffin and Co., 1892.) camera of some sort or other, it is very curious to carry ourselves back to the time of Daguerre and to picture to ourselves the idea which he put forward when he wrote in his pamphlet, "Those persons are deceived who suppose that during a journey they may avail themselves of brief intervals while the carriage slowly mounts a hill to take views of a country." Whether this is or is not the case now we will not stop to discuss, but we may mention that many other very interesting extracts are made from the same source. The next three chapters deal with the chemistry. optics, and light as applied to photography. In these there seems to be nothing that calls for special attention, unless it be to state that the author has written them in a charming manner, as for instance the short summary under the heading Magnesium Light," which one reads with quite renewed interest. 66 Coming now to Part II., Processes, we find the most important section of the whole book. As Mr. Brothers rightly observes, the old processes previous to the introduction of the gelatine bromide methods have been put completely in the shade, not because they have been surpassed by better and more trustworthy ones, but simply because they require a little more care in manipulation and consequently the consumption of more time. In order to remedy this to some extent he has given great prominence to them, dedevoting nearly 140 pages to them, including working details of the more important later processes. For the sake of facility of reference they are arranged in alphabetical order, and in many cases they are accompanied by illustrations which show the actual results that can be obtained by the uses of the methods under consideration. To cite them in anything like detail would carry us too far away, but we may mention one or two briefly. The (wet) collodion process is of course here fully described: the author lays special stress on the advantage of this process, for there is no doubt that where dry plates are now used far better results could be obtained by employing this old wet process. The photo-mechanical process, collotype, receives also a rather lengthy description, but its utility and the excellence of the results obtained necessarily give it some prominence. A specimen illustration of the last mentioned is inserted, as well as one of a recent application of this method for printing in colour. Printing on wood, photo-lithography, platinotype, &c. together with photogravine Woodbury type and a host MR. BROTHERS has in this well-illustrated book of others, are all described, some briefly, others of greater brought together a great amount of information relative to the history, processes, apparatus, materials, &c., which will be welcomed by all who are interested, even if only in a general way, in the fascinating art of photography. The work covers about 360 pages, is divided into five parts and is accompanied by a full index. In the short historical sketch which is introduced as the opening chapter, the author by means of quotations and otherwise gain much information which is not readily accessible, and many facts that are not inserted in our treatises, and which consequently are not generally known. At the present day, when so many possess a importance somewhat more in full. Parts III. and IV. deal with the apparatus and materials used in the production of a finished picture. In the former the author describes the particular characteristics of many of the various kinds of cameras and accessories, while in the latter are explained the chief uses and actions of the chemicals employed. Part V., the last, contains short notices of the applica Astro tions to which photography has given rise. nomical Photography is referred to at some length. and we may mention that we have excellent reproduction of one of Mr. Rutherfurd's beautiful lunar photographs taken at first quarter. The practica an hints in the concluding chapter should be found very serviceable. Mr. Brothers has produced a very serviceable and useful addition to our photographic literature; as a handbook for students it perhaps is somewhat too bulky, but nevertheless it will be very much used by them. Every photographer who wishes to know something about the art with which he is working, and who does not wish to limit himself to the mere cut-and-dried manipulations, should at any rate make himself acquainted with the volume. W. J. L. MATRICULATION CHEMISTRY. the atomic theory. If, according to its usual interpretation, a law is a generalized statement of fact, it is rather hard to see how its existence is affected by its relations to any theory. To most chemists the brilliant work of Moissan has sufficed to settle the question of the isolation of fluorine; the author is, however, still sceptical on this point. PO is given as the formula of phosphorous acid (sic); recent research has shown P,O to be correct. The valency of potassium is said to have been fixed by a "minute study of its gaseous compounds," water is stated to be elastic with regard to shape, and from Avrogadro's hypothesis molecules of different gases are stated to be equal in size. Even when the author is apparently trying to be precise he is apt to mislead. The following definition is an Matriculation Chemistry. By Temple Orme. (London: example :-" A chloride means a compound of chlorine Lawrence and Bullen, 1892.) THIS HIS is still another elementary manual dealing with the non-metals and their compounds. According to the author it can be studied most advantageously if the rudiments of chemistry have first been acquired, The book is built on pretty much the same plan as many already in existence; here and there, however, the reading is enlivened by ideas which, if not altogether commendable, have some pretensions to novelty. The author is evidently of opinion that much of the ordinary chemical knowledge can be presented in other ways. Mass and weight first receive attention. In this book there are no atomic weights; atomic masses reign supreme. In using a balance we are told that we do not find weights, but "only masses." Indeed to bring this idea home the following curious question is set :-" When you weigh' a thing in an ordinary balance, do you find its weight?" · After a passing allusion to constitutional formulæ, in which they are likened to pyrotechnic frames, the next important alteration with which the author concerns himself refers to the nomenclature of oxides. Such a name as sulphur dioxide or carbon dioxide is discarded, for it is "founded upon a formula which is liable at any time to be altered so as to suit our knowledge of atoms and molecules." Anhydride is described as, " etymologically at least, a still more atrocious term "; hence we find that throughout the book SO2, CO,, &c., are spoken of as acids. P2O, is said to be a tribasic acid, NC, a monobasic acid. CS, is called sulphocarbonic acid, PS, thiophosphoric acid, N,O hyponitrous acid, and so forth, in spite of the fact that such compounds as that formed from "hydric oxide and phosphoric acid (sic) are often called acids by modern chemists." The definition of a salt is thus summarily disposed of:-" You are often asked what a salt is; the only possible answer is that it is a compound." Such methods of tampering with terms which have a generally-accepted meaning should, it seems to us, meet with no encouragement. They can only end in muddling the reader who wishes to pursue his subject by the aid of any of our standard works. But matter which is liable to do more immediate harm is frequently to be noted. For instance, it is stated that there is no such thing as he Law of Multiple proportions-it is only a corollary of with some other substance which, though it is not itself metallic in its general characteristics, possesses that important property of a metal, the capability of uniting energetically with chlorine." Is it to be understood from all this that a chlorine compound which is not produced by energetic union-say an endothermic compound like CC-is not a chloride? These extracts may serve to show that the book requires to be carefully overhauled before it can be placed with confidence in the hands of a beginner. OUR BOOK SHELF. Vegetable Wasps and Plant Worms; a Popular History of Entomogenous Fungi, or Fungi parasitic upon Insects. By M. C. Cooke, M.A., LL.D., A.L.S. [364 pp. 4 pl. and figs. in text] (London: S.P.C.K., 1892.) IT is somewhat surprising that a book on a subject of such importance alike to the entomologist and fungologist has not been forthcoming long ago. It is true that a Memoir on the subject was undertaken thirty-five years ago by Mr. G. R. Gray, but, being privately printed, was limited in circulation. To this work Dr. Cooke admits his indebtedness for a large amount of information bearing on the entomological aspect of the subject, and it is to be regretted that he was not aware of the existence of a much extended manuscript revision of the same work, Museum. at present in the Botanical Department, Natural History Dr. Cooke's book is professedly a popular work on the subject, and consequently does not deal with the economic side, relating to such matters as the "muscardine" or silkworm disease, further than to indicate the nature and affinities of the fungus causing the disease. The fungi parasitic upon insects are arranged under four primary groups: the Cordyceps group, the Laboulbeniacea; the Entomophthora, and lastly a heterogeneous collection of moulds, which, with few exceptions, are not truly parasitic and destructive. The structure of their life-history, are dealt with in an introductory and general characteristics of these groups, with glimpses chapter. Entomologists, whose main interest will be to ascertain the name of any fungus parasitic on an insect, will find this a comparatively easy matter, as the general arrangement is an entomological one, commencing with the Hymenoptera; and under each is given an account of all the fungi that are known to be parasitic upon species included in the order. Numerous woodcuts in the text and four plates assist very materially in the determination of species. From the mycological standpoint the arrangement indicated above is purely artificial, and introduced |